Journal
TETRAHEDRON LETTERS
Volume 48, Issue 6, Pages 989-992Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.12.009
Keywords
enantiospecific synthesis; abietane diterpenoids; lactones
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A new route to 12-hydroxyabictic acid (10) and related compounds from abietic acid (12), via acetoxyalcohol 15, is reported. Utilizing this, the first synthesis of picealactone C (5) was achieved. The synthesis of natural 12-hydroxydehydroabietic acid (8), 18-hydroxyferruginol (9) and methyl 12 alpha-hydroxyabietate (11) is also reported. (c) 2006 Elsevier Ltd. All rights reserved.
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