4.8 Article

Metal-Free Triplet Phosphors with High Emission Efficiency and High Tunability

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 25, Pages 6378-6382

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201402199

Keywords

dual emission; excimer; organic emitter; phosphorescence

Funding

  1. Swiss National Science Foundation NRP 62 Smart Materials Program [406240-126142]
  2. University of Zurich
  3. Swiss National Science Foundation (SNF) [406240_126142] Funding Source: Swiss National Science Foundation (SNF)

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Design of highly efficient phosphorescent emitters based on metal- and heavy atom-free boron compounds has been demonstrated by taking advantage of the singlet fission process. The combination of a suitable molecular scaffold and appropriate electronic nature of the substituents has been utilized to tailor the phosphorescence emission properties in solution, neat solid, and in doped PMMA thin films.

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