Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 43, Pages 11587-11591Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201406304
Keywords
donor-acceptor systems; Group13 elements; heterometallic complexes; main-group elements; metal-metal interactions
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Funding
- University of Duisburg-Essen
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Monovalent RAl (R=HC[C(Me)N(2,6-iPr(2)C(6)H(3))](2)) reacts with E2Et4 (E=Sb, Bi) with insertion into the weak EE bond and subsequent formation of RAl(EEt2)(2) (E=Sb 1; Bi 2). The analogous reactions of RGa with E2Et4 yield a temperature-dependent equilibrium between RGa(EEt2)(2) (E=Sb 3; Bi 4) and the starting reagents. RIn does not interact with Sb2Et4 under various reaction conditions, but formation of RIn(BiEt2)(2) (5) was observed in the reaction with Bi2Et4 at low temperature.
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