Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 7, Pages 1822-1826Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201309546
Keywords
boron; CH functionalization; chemoselectivity; homogeneous catalysis; synthetic methods
Categories
Funding
- NSFC [21202129]
- MOST [2014CB548200]
- Xi'an Jiaotong University
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Di- and polyboron (hetero)arenes, site-differentiated with MIDA boronyl (MIDA=N-methyliminodiacetic acid) and pinacolato boronyl (Bpin), were prepared by an iridium-catalyzed direct CH borylation of readily available (hetero)aryl MIDA boronates. The excellent synthetic uses of these multisite nucleophiles were demonstrated by the high-yield production of a variety of multifunctionalized poly(hetero)arenes with the highly chemoselective Suzuki-Miyaura coupling (SMC) of the Bpin moiety being an essential step.
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