Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 10, Pages 2754-2758Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310272
Keywords
CH activation; isoquinolones; ketones; N-heterocycles; rhodium catalysis
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Funding
- Alexander von Humboldt Foundation
- Sao Paulo Research Foundation [2013/14209-9]
- European Research Council (ERC) under the European Community [25936]
- DFG
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-Halo and pseudohalo ketones are used for the first time as C(sp(3))-based electrophiles in transition-metal-catalyzed CH activation and as oxidized alkyne equivalents in Rh-III-catalyzed redox-neutral annulations to generate diverse N-heterocycles. This transformation is efficient and scalable. Due to the mild reaction conditions, a variety of functional groups could be tolerated.
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