Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 10, Pages 2658-2661Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201400147
Keywords
asymmetric catalysis; C-H functionalization; iridium; oxindoles; phosphoramidites
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Funding
- MEXT (Japan) program Strategic Molecular and Materials Chemistry through Innovative Coupling Reactions of Hokkaido University
- Grants-in-Aid for Scientific Research [14J01208] Funding Source: KAKEN
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Asymmetric intramolecular direct hydroarylation of -ketoamides gives various types of optically active 3-substituted 3-hydroxy-2-oxindoles in high yields with complete regioselectivity and high enantioselectivities (84-98% ee). This is realized by the use of the cationic iridium complex [Ir(cod)(2)](BAr4F) and the chiral O-linked bidentate phosphoramidite (R,R)-Me-BIPAM.
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