Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 49, Pages 13578-13582Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201408467
Keywords
C-F activation; ligand effects; palladium; regioselectivity; structure elucidation
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Funding
- MEXT [21245028, 25708018, 23105546]
- Grants-in-Aid for Scientific Research [25105736, 25708018] Funding Source: KAKEN
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A chemoselective C(sp(2))-F or C(sp(3))-F bond activation of hexafluoropropylene (HFP) was achieved by adopting the proper combination of a Lewis acid co-additive with a ligand which coordinates Pd-0. The treatment of [(eta(2)-HFP) Pd(PCy3)(2)] with B(C6F5)3 allowed a chemoselective C-(sp(3))-F bond cleavage of HFP to give a unique cationic perfluoroallypalladium complex. In this complex, the coordination mode of the perfluoroallyl ligand was considered to be of the unique eta(2)-fashion.
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