Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 48, Pages 13210-13214Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201407676
Keywords
ADOR; germanosilicates; porosity; zeolites
Categories
Funding
- Royal Society
- EPSRC [EP/K025112/1, EP/L014475/1]
- Czech Science Foundation [P106/12/G015]
- European Community
- EPSRC [EP/K025112/1, EP/L014475/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/L014475/1, EP/K025112/1] Funding Source: researchfish
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Zeolites are important materials whose utility in industry depends on the nature of their porous structure. Control over microporosity is therefore a vitally important target. Unfortunately, traditional methods for controlling porosity, in particular the use of organic structure-directing agents, are relatively coarse and provide almost no opportunity to tune the porosity as required. Here we show how zeolites with a continuously tuneable surface area and micropore volume over a wide range can be prepared. This means that a particular surface area or micropore volume can be precisely tuned. The range of porosity we can target covers the whole range of useful zeolite porosity: from small pores consisting of 8-rings all the way to extra-large pores consisting of 14-rings.
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