Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 18, Pages 4699-4703Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310455
Keywords
DFT calculations; lead; MP2 calculations; plumbates; structure elucidation
Categories
Funding
- Deutsche Forschungsgemeinschaft [SPP 1415]
- Friedrich Ebert Stiftung
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The first inorganic lead(IV) compound without oxygen, nitrogen or halogen ligands attached to the lead atom was obtained as the potassium salt of the tetraselenidoplumbate(IV) anion [(PbSe4)-Se-IV](4-). It is stable under inert conditions which may enable the transfer of the chemistry of chalcogenidogermanate(IV) or chalcogenidostannate(IV) materials, to the lead homologues.
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