Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 1, Pages 114-117Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201408438
Keywords
fullerenes; liquid crystals; pi interactions; self-assembly; X-ray diffraction
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Funding
- National Natural Science Foundation of China [21074079, 21274099]
- Priority Academic Program Development of Jiangsu Higher Education
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Fullerene-based liquid crystalline materials have both the excellent optical and electrical properties of fullerene and the self-organization and external-field-responsive properties of liquid crystals (LCs). Herein, we demonstrate a new family of thermotropic [60]fullerene supramolecular LCs with hierarchical structures. The [60]fullerene dyads undergo self-organization driven by -interactions to form triple-layer two-dimensional (2D) fullerene crystals sandwiched between layers of alkyl chains. The lamellar packing of 2Dcrystals gives rise to the formation of supramolecular LCs. This design strategy should be applicable to other molecules and lead to an enlarged family of 2Dcrystals and supramolecular liquid crystals.
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