Journal
TETRAHEDRON LETTERS
Volume 48, Issue 7, Pages 1225-1227Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.12.061
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The synthesis of a novel oxazolidinone sialosyl donor is reported. The introduction of a trans-fused ring enhances reactivity and stereoselectivity in glycosylation reactions for the synthesis of alpha-sialosides. The oxazolidinone ring can also be removed under basic conditions to afford the deprotected amine, which can be further functionalized. (c) 2006 Elsevier Ltd. All rights reserved.
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