Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 263, Issue 1-2, Pages 39-47Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2006.08.015
Keywords
Hoveyda's catalyst; inisurf; ring-opening metathesis polymerization; ring-closing metathesis; surfactant
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Metathesis catalysts bearing long alkyl chains and analogous to Hoveyda's catalyst have been synthesized. Their surface-active properties have been characterized by formation of Langmuir films at the air-water interface. They have been dispersed in micelles formed in non-degassed water and been used in polymerization of a hydrophilic monomer. These surfactants are therefore the first inisurf molecules for metathesis polymerization that are air-stable. Their ability to catalyze ring-closing metathesis in water has also been evaluated. (c) 2006 Elsevier B.V. All rights reserved.
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