Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 6, Pages 1506-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja0666147
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- NCRR NIH HHS [C06RR-16572] Funding Source: Medline
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A chiral tripodal ligand readily prepared from primary amines that contains two monosubstituted tetraphenylporphyrin (TPP) moieties is described. Complexation with Cu(II) in the presence of NH4SCN gives a fully metalated porphyrin and tripoda l ligand complex. The free ligand shows a weak circular dichroism (CD) signal, but metalation gives a strong exciton-coupled CD spectrum. Reduction of the Cu(II) complex results in loss of CD signal.
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