Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 44, Pages 11868-11871Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201407948
Keywords
C-H activation; electrochemistry; heterocycles; radical reactions; reaction mechanisms
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Funding
- NIH/NIGMS [GM-106210]
- Pfizer Inc
- Teijin Pharma Ltd
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Electrochemical reactions are shown to be effective for the C-H functionalization of a number of heterocyclic substrates that are recalcitrant to conventional peroxide radical initiation conditions. Monitoring reaction progress under electrochemical conditions provides mechanistic insight into the C-H functionalization of a series of heterocycles of interest in medicinal chemistry.
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