Journal
ORGANIC LETTERS
Volume 9, Issue 4, Pages 675-678Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol062824c
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A metal-directed self-assembly of [3]catenanes in combination with pi-pi interactions was investigated. Ligands based on 4,4'-bipyridinium or 2,7-diazapyrenium were used in conjunction with dioxoaryl cyclophanes (4-6) and trans-PdCl2(CH3CN)(2). The [3]catenanes show a dinuclear palladium 46-membered metallomacrocycle interlocked by two pi-complementary dioxoaryl macrocycles.
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