Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 41, Pages 11027-11031Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201406044
Keywords
BiFeO3; charge transfer; photoelectrodes; polarization; tunability
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Funding
- European Research Council [ThreeDsurface: 240144]
- BMBF [ZIK-3DNanoDevice: 03Z1MN11]
- Volkswagen-Stiftung [Herstellung funktionaler Oberflachen: I/83 984]
- Shanghai Thousand Talent Plan and Innovative Research Team [IRT13078]
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Instead of conventional semiconductor photoelectrodes, herein, we focus on BiFeO3 ferroelectric photoelectrodes to break the limits imposed by common semiconductors. As a result of their prominent ferroelectric properties, the photoelectrodes are able to tune the transfer of photo-excited charges generated either in BiFeO3 or the surface modifiers by manipulating the poling conditions of the ferroelectric domains. At 0 V vs Ag/AgCl, the photocurrent could be switched from 0 mu A cm(-2) to 10 mu A cm(-2) and the open-circuit potential changes from 33 mV to 440 mV, when the poling bias of pretreatment is manipulated from -8 V to +8 V. Additionally, the pronounced photocurrent from charge injection of the excited surface modifiers could be quenched by switching the poling bias from +8 V to -8 V.
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