Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 30, Pages 7892-7895Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201404320
Keywords
alkynes; bipyridines; homogeneous catalysis; hydration; ruthenium
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Funding
- David and Lucile Packard Foundation
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Anti-Markovnikov alkyne hydration provides a valuable route to aldehydes. Half-sandwich ruthenium complexes ligated by 5,5'-bis(trifluoromethyl)-2,2'-bipyridine are remarkably active for this transformation. In the presence of 2 mol% metal, a wide range of functionalized aliphatic and aromatic alkynes are hydrated in high yield at ambient temperature.
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