Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 111, Issue 6, Pages 1443-1448Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp067039w
Keywords
-
Categories
Ask authors/readers for more resources
An analytical model is developed for the potential drop and differential capacity across the diffuse layer which considers the effects of ion size on these properties. For symmetric electrolytes, this potential drop is expressed in terms of a cubic polynomial in the corresponding estimate in the Gouy-Chapman theory. Optimal polynomial coefficients and model validation for 1:1 and 2:2 electrolytes are provided by fits of Monte Carlo data obtained for a restricted electrolyte in a primitive solvent. Simple relationships between these coefficients and parameters commonly associated with the mean spherical approximation are obtained. It is shown that the series approach accurately describes potential drops and differential capacities of the diffuse layer for 1:1 and 2:2 electrolytes for the chosen assumptions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available