4.8 Article

A Photo-annealing Approach for Building Functional Polymer Layers on Paper**

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 17, Pages 4465-4468

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310714

Keywords

conducting materials; gas sensors; paper devices; polymers; photo-annealing

Funding

  1. National Natural Science Foundation of China [51373197]
  2. Trans-Century Training Programme Foundation for the Talents by the State Education Commission [NCET-12-0530]
  3. Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application (Soochow University)

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A straightforward photo-annealing approach was developed for building functional polymer layers on paper. Conducting polyaniline with the ability for photothermal conversion can be readily annealed by near-infrared light. The annealed polymers become both insulating and hydrophobic. Selective photo-annealing produces a functional layer with patterned conductive arrays. This material exhibits real-time response to ammonium gas. Complete photo-annealing preserves the porous structure but changes the wettability of the polyaniline-nanofiber film.

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