Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 42, Pages 11228-11231Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201406223
Keywords
conducting materials; molecular electronics; nanoparticles; polyoxometalates
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Funding
- Network Joint Research Centre for Materials and Devices of Japan
- Ministry of Education, Culture, Sports, Science and Technology of Japan
- Grants-in-Aid for Scientific Research [26102007, 23245027, 24750129, 14J05886] Funding Source: KAKEN
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In a mixed-valence polyoxometalate, electrons are usually delocalized within the cluster anion because of low level of inter-cluster interaction. Herein, we report the structure and electrical properties of a single crystal in which mixed-valence polyoxometalates were electrically wired by cationic -molecules of tetrathiafulvalene substituted with pyridinium. Electron-transport characteristics are suggested to represent electron hopping through strong interactions between cluster and cationic pi-molecules.
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