Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 600, Issue 2, Pages 311-317Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2006.10.002
Keywords
copper; progressive and instantaneous nucleation; current transients
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The nucleation and growth of copper crystals on a glassy carbon electrode are investigated at different constant overpotentials. Current transients are recorded and the number of copper nuclei is microscopically registered. The experimental data for the growth current are interpreted according to the theories of progressive and instantaneous nucleation and information is obtained on the stationary nucleation rate, the saturation nucleus number density and the exchange current density Lit the crystal-solution interface boundary. (c) 2006 Elsevier B.V. All rights reserved.
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