4.7 Article

Domino carbocationic rearrangement of α-[bis(methylthio)methylene]alkyl-2-(3/2-indolyl) cyclopropyl ketones

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 4, Pages 1388-1394

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo062302a

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[GRAPHIC] Domino carbocationic rearrangement of a number of substituted 3- and 2-indolylcyclopropyl ketones with an alpha-bis(methylthio)methylene group in the presence of various protic/Lewis acids yields a variety of products, mainly the pentaleno fused indoles and the carbazole derivatives.

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