4.8 Article

Photocatalytic Au-Bi2S3 Heteronanostructures

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 26, Pages 6743-6746

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201402709

Keywords

bismuth; gold; electron transfer; heterostructures; photocatalysts

Funding

  1. DST Swarnajayanti [DST/SJF/CSA-01/2010-2012]

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Au-Bi2S3 heteronanostructure photocatalysts were designed in which the coupling of a metal plasmon and a semiconductor exciton aids the absorption of solar light, enhances charge separation, and results in improved catalytic activity. Furthermore, these nanostructures show a unique pattern of structural combination, with Au nanoparticles positioned at the center of Bi2S3 nanorods. The chemistry of formation of these nanostructures, their epitaxy at the junction, and their photoconductance were studied, as well as their photoresponse properties.

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