Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 4, Pages 1541-1544Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo062426n
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The aromatic ketone 2,2',4,4'-tetramethoxybenzophenone has a strong absorption band between 300 and 375 nm, and its pi,pi* triplet excited-state is selectively populated in methanol. Both facts make this aromatic ketone a versatile and efficient triplet photocatalyst for the transformation of alpha-diazo carbonyl compounds into mainly the cyclopropanation product.
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