Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 24, Pages 6180-6183Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201403587
Keywords
asymmetric catalysis; chiral Bronsted acids; Nazarov cyclization; quaternary stereocenters
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The diastereoselective asymmetric synthesis of vicinal all-carbon-atom quaternary stereocenters is a challenging problem in organic synthesis for which only few solutions have been described. A catalytic asymmetric Nazarov cyclization of fully substituted dienones that provides cyclopentenone derivatives with vicinal quaternary stereocenters in high optical purity and as single diastereoisomers is now reported.
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