Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 827, Issue 1-3, Pages 195-200Publisher
ELSEVIER
DOI: 10.1016/j.molstruc.2006.05.029
Keywords
cuprous(I) iodide complexes; crystal structure; luminescence properties
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Solution reaction of Cull) iodide with organic multifunctional ligands generated two different structure motifs: OD cluster [(CuI)(2)(dpdS)(2)] 1 (dpds = 2,2'-dipyridyldisulfide), and 1D polymer [(CuI)(bbbm)](n) 2 (bbbm = 1,1'-(1,4-butanediyl)bis-1H-benzimidazole). Both compounds contain the flexible rhomboid Cu2I2 cluster unit. The solution-state luminescence spectra showed that the high-energy emission may be associated with a metal-to-ligand [Cu -> pi*(pyridine)] or ligand-to-ligand [I- -> n*(pyridine)] charge-transfer excited state. (c) 2006 Elsevier B.V. All rights reserved.
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