Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 35, Pages 9347-9351Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201404611
Keywords
cations; homogeneous catalysis; hydrides; N-heterocyclic carbene; zinc
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Funding
- NSERC Canada
- Alberta Innovates Technology Futures
- Canada Foundation for Innovation (CFI)
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We present isolable examples of formal zinc hydride cations supported by N-heterocyclic carbene (NHC) donors, and investigate the dual electrophilic and nucleophilic (hydridic) character of the encapsulated [ZnH](+) units by computational methods and preliminary hydrosilylation catalysis.
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