Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 15, Pages 3957-3960Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201309836
Keywords
CO2 capture; functional nanocarbons; supercapacitors; ATRP
Categories
Funding
- Guangdong Natural Science Funds for Distinguished Young Scholar [S2013050014408]
- NSFC [51173213, 51372280, 51172290, 51232005]
- Program for New Century Excellent Talents in University [NCET-12-0572]
- Program for Pearl River New Star of Science and Technology in Guangzhou [2013J2200015]
- Fundamental Research Funds for the Central Universities [13lgpy57]
- National Key Basic Research Program of China [2014CB932402]
- NSF [DMR-0969301]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [969301] Funding Source: National Science Foundation
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A facile templated synthesis of functional nanocarbon materials with well-defined spherical mesopores is developed using all-organic porogenic precursors comprised of hairy nanoparticles with nitrogen-rich polyacrylonitrile shells grafted from sacrificial cross-linked poly(methyl methacrylate) cores (xPMMA-g-PAN). Such shape-persistent all-organic nanostructured precursors, prepared using atom transfer radical polymerization (ATRP), assure robust formation of template nanostructures with continuous PAN precursor matrix over wide range of compositions, and allow for removal of the sacrificial template through simple thermal decomposition. Carbon materials prepared using this method combine nitrogen enrichment with hierarchical nanostructure comprised of microporous carbon matrix interspersed with mesopores originating from sacrificial xPMMA cores, and thus perform well as CO2 adsorbents and as supercapacitor electrodes.
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