4.7 Article

Reverse photochromic behavior of an iron-magnesium complex

Journal

INORGANIC CHEMISTRY
Volume 46, Issue 4, Pages 1039-1041

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic0616986

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We have obtained a novel heterobimetallic iron-magnesium complex, (THF)(4)Mg(mu-Br)(2)FeBr2 (THF = tetrahydrofuran), which showed reverse photochromism in THF. The response exhibited in this system is associated with d-orbital splitting of the Fe atom and a change in the molecular aggregation state (dimerization).

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