Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 26, Pages 6791-6794Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201403823
Keywords
alpha-arylation; C-O activation; nickel; oxidative addition; synthetic methods
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Funding
- JSPS [220GR049]
- MEXT [25105720, 25708005]
- JSPS
- World Premier International Research Center (WPI) Initiative (Japan)
- Grants-in-Aid for Scientific Research [25105720, 13J03280, 25708005] Funding Source: KAKEN
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The nickel-catalyzed alpha-arylation of ketones with readily available phenol derivatives (esters and carbamates) provides access to useful alpha-arylketones. For this transformation, 3,4-bis(dicyclohexylphosphino)thiophene (dcypt) was identified as a new, enabling, air-stable ligand for this transformation. The intermediate of an assumed C-O oxidative addition was isolated and characterized by X-ray crystal-structure analysis.
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