Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 4, Pages 1034-1038Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201309426
Keywords
carbon dioxide; cobalt; metal-organic frameworks; photochemistry; zeolites
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Funding
- National Basic Research Program of China [2013CB632405, 2014CB239303]
- National Natural Science Foundation of China [21033003, 21273039]
- State Key Laboratory of NBC Protection for Civilian [SKLNBC2013-04K]
- Specialized Research Fund for the Doctoral Program of Higher Education [20133514110003]
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Metal-organic frameworks (MOFs) have shown great promise for CO2 capture and storage. However, the operation of chemical redox functions of framework substances and organic CO2-trapping entities which are spatially linked together to catalyze CO2 conversion has had much less attention. Reported herein is a cobalt-containing zeolitic imidazolate framework (Co-ZIF-9) which serves as a robust MOF cocatalyst to reduce CO2 by cooperating with a ruthenium-based photosensitizer. The catalytic turnover number of Co-ZIF-9 was about 450 within 2.5hours under mild reaction conditions, while still keeping its original reactivity during prolonged operation.
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