4.8 Article

Photoswitchable molecular lock. One-way catenation of a Pt(II)-linked coordination ring via the photolabilization of a Pt(II)-pyridine bond

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 7, Pages 1850-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja067132y

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An inert Pt(II)-py bond (py = pyridyl) is considerably labilized upon UV irradiation. On the basis of this phenomenon, a kinetically inert Pt(II)-linked coordination ring is rapidly catenated on irradiation via Pt(II)-py photodissociation.

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