4.8 Article

Facile heterolytic cleavage of dihydrogen by phosphines and boranes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 7, Pages 1880-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja067961j

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The facile heterolytic cleavage of H-2 is readily achieved at room temperature by the cooperative action of the Lewis acidic borane and Lewis basic phosphine, where the steric congestion precludes quenching of the acid and base via adduct formation.

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