Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 52, Issue 18, Pages 4744-4788Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201204921
Keywords
cooperative catalysis; NH effect; organometallic catalysis; self-assembly; supramolecular catalysis
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Funding
- NSFC [21121062, 21032007, 91127041]
- Major Basic Research Development Program of China [2010CB833300]
- Chinese Academy of Sciences
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The organometallic approach is one of the most active topics in catalysis. The application of NH functionality in organometallic catalysis has become an important and attractive concept in catalyst design. NH moieties in the modifiers of organometallic catalysts have been shown to have various beneficial functions in catalysis by molecular recognition through hydrogen bonding to give catalystsubstrate, ligandligand, ligandcatalyst, and catalystcatalyst interactions. This Review summarizes recent progress in the development of the organometallic catalysts based on the concept of cooperative catalysis by focusing on the NH moiety.
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