Journal
ORGANOMETALLICS
Volume 26, Issue 5, Pages 1157-1160Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om0609158
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The hydrosilylation of terminal alkynes is catalyzed by [Cp*IrCl2](2) to afford selectively the beta-(Z)-vinylsilanes in high yields. A catalytic cycle based on an Ir(III)-Ir(V) redox process is proposed.
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