Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 52, Issue 28, Pages 7084-7097Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201300942
Keywords
heterocycles; homogeneous catalysis; isocyanides; palladium; synthetic methods
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Funding
- Netherlands Organization for Scientific Research (NWO)
- University of Antwerp
- Hercules Foundation
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Isocyanides have been important building blocks in organic synthesis since the discovery of the Ugi reaction and related isocyanide-based multicomponent reactions. In the past decade isocyanides have found a new application as versatile C-1 building blocks in palladium catalysis. Palladium-catalyzed reactions involving isocyanide insertion offer a vast potential for the synthesis of nitrogen-containing fine chemicals. This Minireview discusses all the achievements in this emerging field.
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