Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 5, Pages 1364-1367Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201309650
Keywords
C-H activation; diazo compounds; homogeneous catalysis; metal-carbene complexes; migratory insertion
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Funding
- National Basic Research Program of China (973 Program) [2012CB821600]
- National Natural Science Foundation of China [21272010, 21332002]
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A coupling reaction of N-phenoxyacetamides with N-tosylhydrazones or diazoesters through Rh-III-catalyzed C-H activation is reported. In this reaction, ortho-alkenyl phenols were obtained in good yields and with excellent regio- and stereoselectivity. Rh-carbene migratory insertion is proposed as the key step in the reaction mechanism.
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