Journal
CHEMICAL PHYSICS LETTERS
Volume 436, Issue 1-3, Pages 204-208Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2007.01.039
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Irradiation of powdered TiO2 by atomic hydrogen has been shown to produce electron-hole pairs in the TiO2. The electronic excitation from shallow traps is measured in the IR region by absorption spectroscopy, where IR photons excite H-atom derived electrons into the conduction band continuum. The activation energy for atomic H diffusion into the TiO2 crystal lattice is low: 0.09 +/- 0.01 eV. D atom substitution for H does not influence the kinetics of production of shallow-trap electrons nor of their decay. (c) 2007 Published by Elsevier B.V.
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