Journal
TETRAHEDRON-ASYMMETRY
Volume 18, Issue 3, Pages 372-376Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2007.02.004
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Novel chiral spiro bis(isoxazoline) ligands 3 and 4 are synthesized from an optically active olefin. The Cu(II)-spiro bis(isoxazoline) complex prepared in situ from Cu(OTf)(2) and 3 promoted the glyoxylate-ene reaction in high yield and moderate enantioselectivity (up to 70%). (c) 2007 Published by Elsevier Ltd.
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