4.8 Article

Competing supramolecular assembly of amphiphiles to form micelles or pseudorotaxanes

Journal

ORGANIC LETTERS
Volume 9, Issue 5, Pages 887-890

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol063137o

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Micelles of an amphiphile that encapsulate the added dye in water can be released, upon addition of alpha-CD, to form pseudorotaxane. The equilibrium between the micelles and the pseudorotaxanes and the absorption spectra of solution are controlled by temperature reversibly.

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