Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 3, Pages 793-797Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201308820
Keywords
azides; energy transfer; nitrenes; nitrogen heterocycles; photocatalysis
Categories
Funding
- NIH [GM095666]
- Sloan Foundation
- NSF [CHE-1048642]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1048642] Funding Source: National Science Foundation
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Irradiation of vinyl and aryl azides with visible light in the presence of Ru photocatalysts results in the formation of reactive nitrenes, which can undergo a variety of C-N bond-forming reactions. The ability to use low-energy visible light instead of UV in the photochemical activation of azides avoids competitive photodecomposition processes that have long been a significant limitation on the synthetic use of these reactions.
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