Journal
MOLECULAR PHYSICS
Volume 105, Issue 5-7, Pages 559-568Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00268970601099261
Keywords
-
Ask authors/readers for more resources
A total of 3155 vibration-rotation line positions providing accurate information on all known vibration-rotation states up to 3000 cm(-1) in (C2H2)-C-12 were gathered from the literature. An additional 966 lines were assigned on new spectra. The full data set was simultaneously fitted using an appropriate Hamiltonian, with 85 refined parameters. A dimensionless standard deviation equal to 0.86, accounting for 92% of the lines, was achieved. The vibrational transition dipole moment of the v(5) = 1 <- v(4) = 1 band observed in the far-infrared was estimated to be vertical bar mu(5 <- 4)vertical bar = 0.55 D with 20% accuracy, from absolute intensity measurements for a few Q-branch lines.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available