Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 53, Issue 1, Pages 127-131Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201308541
Keywords
C-H bond functionalization; Mizoroki-Heck reaction; ozagrel; palladium nanoparticle; silicon-nanowire array
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Funding
- JST ACT-C
- JST CREST
- JSPS [24550126, 20655035, 2105]
- Takeda Science Foundation
- Naito Foundation
- RIKEN
- Grants-in-Aid for Scientific Research [24550126, 24106744] Funding Source: KAKEN
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We report the development of a silicon nanowire array-stabilized palladium nanoparticle catalyst, SiNA-Pd. Its use in the palladium-catalyzed Mizoroki-Heck reaction, the hydrogenation of an alkene, the hydrogenolysis of nitrobenzene, the hydrosilylation of an ,-unsaturated ketone, and the C-H bond functionalization reactions of thiophenes and indoles achieved a quantitative production with high reusability. The catalytic activity reached several hundred-mol ppb of palladium, reaching a TON of 2000000.
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