Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 180, Issue 3, Pages 1038-1044Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2006.12.034
Keywords
solvothermal; ZnFe2O4; gamma-Fe2O3; diphase nanostructure; superparamagnetic
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Magnetic diphase nanostructures of ZnFe2O4/gamma-Fe2O3 were synthesized by a solvothermal method. The formation reactions were optimized by tuning the initial molar ratios of Fe/Zn. All samples were characterized by X-ray diffraction, thermogravimetric analysis, infrared spectroscopy, and Raman spectra. It is found that when the initial molar ratio of Fe/Zn is larger than 2, a diphase magnetic natiostructure of ZnFe2O4/gamma-Fe2O3 was formed, in which the presence of ZnFe2O4 enhanced the thermal stability of gamma-Fe2O3. Further increasing the initial molar ratio of Fe/Zn larger than 6 destabilized the diphase nanostructure and yielded traces of secondary phase alpha-Fe2O3. The grain surfaces of diphase nanostructure exhibited a spin-glass-like structure. At room temperature, all diphase nanostructures are superparamagnetic with saturation magnetization being increased with gamma-Fe2O3 content. (c) 2007 Elsevier Inc. All rights reserved.
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