Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 52, Issue 52, Pages 14162-14166Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201307224
Keywords
homogeneous catalysis; hydrogen; iron catalysts; methanol; renewable energy
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Molecularly well-defined iron pincer complexes promote the aqueous-phase reforming of methanol to carbon dioxide and hydrogen, which is of interest in the context of a methanol and hydrogen economy. For the first time, the use of earth-abundant iron complexes under mild conditions for efficient hydrogen generation from alcohols is demonstrated.
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