Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 52, Issue 49, Pages 12786-12798Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201304555
Keywords
bond angles; fenestranes; planar tetracoordinate carbon atom; strained molecules; synthetic methods
Categories
Funding
- CNRS
- MENRT
- Prestwick Chemical-Illkirch France
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The scaffold of fenestranes is quite unique, as it contains four condensed cycles and a distorted tetracoordinated central carbon atom with bond angles greater than the regular 109 degrees 28. In this Minireview, a detailed overview on the developments regarding this compound class, including their synthesis, is given for the time period since 2006. In the past years, natural products that belong to the class of heterofenestranes have been isolated and their syntheses will also be discussed.
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