Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2007, Issue 8, Pages 1262-1266Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200600873
Keywords
chemo-enzymatic synthesis; tetraols; isoprenoids; carbohydrates
Categories
Ask authors/readers for more resources
By a combination of stereospecific osmium catalyzed oxidation of dimethyl citraconate and lipase catalysed enantioselective resolution of the formed dimethyl (2R*,3S*)-2,3-dihydroxy-2-methylbutanedioate, followed by reduction, (2R,3S)- and (2S,3R)-2-methylbutane-1,2,3,4-tetraol were isolated. Similar reactions starting with dimethyl mesaconate gave the isomers, (2R,3R)- and (2S,3S)-2-methylbutane-1,2,3,4-tetraol. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available