Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 51, Issue 38, Pages 9492-9510Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201202750
Keywords
addenda atoms; cluster compounds; heteropolyanions; noble metals; polyoxometalates
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Funding
- German Science Foundation [DFG-IZ-60/1-1, DFG-KO-2288/9-1]
- Jacobs University
- Graduate School of Georgetown University
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Polyoxometalates containing noble metal ions, such as ruthenium, osmium, rhodium, palladium, platinum, silver and gold, are a structurally diverse class of compounds. They include both classical heteropolyanions (vanadates, molybdates, tungstates) in which noble metals are present as heteroatoms, as well as the recently discovered class of polyoxometalates with noble metal addenda atoms. The focus of this Review is on complexes that should, in principle, exist as discrete molecular species in solution, and which are therefore of interest for their reactivity, their future synthetic utility and potential applications, for example, in catalysis or nanoscience.
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