Journal
CATALYSIS COMMUNICATIONS
Volume 8, Issue 3, Pages 379-382Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2006.07.007
Keywords
titanium silicalite-1; allyl chloride; epoxidation; epichlorohydrin; selectivity; heterogeneous catalysis
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In a mixed solvent system of acetonitrile and methanol, titanium silicate molecular sieve, TS-1, having MFI topology, efficiently catalyses the epoxidation of allyl chloride to the corresponding epichlorohydrin in excellent yields using dilute hydrogen peroxide (45%) as an oxidizing agent. (c) 2006 Elsevier B.V. All rights reserved.
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