☆ 4.8 Article

The Origins of Dramatic Axial Ligand Effects: Closed-Shell MnVO Complexes Use Exchange-Enhanced Open-Shell States to Mediate Efficient H Abstraction Reactions

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

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Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 51, Issue 18, Pages 4421-4425

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201200689

Keywords

density functional calculations; exchange-enhanced reactivity; high-valent Mn-oxo; hydrogen atom abstraction

Categories

Chemistry, Multidisciplinary

Funding

  1. Minerva

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